● The Group 1 metals is known as Alkali Metals (except Hydrogen).『在G1的金属都是碱性的- 如果用石蕊试纸去测试,红色石蕊试纸会变蓝色 * Hydrogen在Room Temperature的时候是气体』
● Elements in this group are Lithium,Sodium,Potassium,Rubidium,Caesium and Fransium.
● All alkali metals are very reactive.They must be stored in oil (paraffin oil)prevent reaction with oxygen or water vapour in air. 『G1的金属都很Reactive,所以要放进Paraffin Oil里面,防止G1金属和空气中的水分和氧气产生化学反应』
● They are all with one valence electron.
** Physical
Properties
● lower melting points and boiling points compared to other metals.
● very soft (can be easily cut by knife)
● good conductors of heat and electricity
● low density (first three floats on water)
** Size
of Atom increases
** Density
increases
● Density of a substance is given by the equation.
● Down the group,both the mass and the volume increase,but increase of mass is faster than the volume,hence the density increases down the group.『重量和体积一样增加,只不过重量比体积增加得快』
** Melting
and Boiling Points Decreases
● All the atoms of Group 1 metals are bonded together by a force called metallic bond.
● The nearer the atoms,the stronger the bond.
● Down the group,the size of the atoms increases,causing the distance of the atoms increases.
● As the distance between the atoms increases,the metallic bond between the atoms decreases.
● Therfore,less energy is needed to overcome the metallic bond during melting process.
● Consequently,the melting point of Group 1 metal decreases down the group.
● Atomic size increases causing the metal bond between atoms become weaker.
** Chemical
Properties
● Lithium,Sodium,and Potassium have similar chemical properties(all of the atoms have one valence electron)but differ in reactivity(reactivity increases down the group, the electropositivity also increases down the group)
● They tend to react mainly with non-metals to form ionic compounds.
The electopositivity of an element is the tendency of the atom of the element to release its electrons(to form positive ion)
● Alkali metals have one valence electrons in their outermost occupied shell.
● When the atoms reacts,it loses the valence electron to form a positively charged ion to achieve the stable duplet / octet electron arrangement.
Lithium,Sodium and Potassium show similar chemical properties.
Explaining
the Reactivity Trend / Electropositivity of the Grouo 1 Alkali Metals.
● As we go down the group,the atomic radius / size increases.
● The valence electron is further from the nucleus.Thus the attraction force between the nucleus and the valence electron become weaker.
● This causes the valence electron is easier to be released to form an ion when the atom takes part in a reaction.
● So,reactivity / electropositivity increases.
Reactions
of Group 1 metals
Reaction
with water,H2O
● to produce metal hydroxide and hydrogen gas.
● Lithium + Water → Lithium Hydroxide + Hydrogen Gas
2Li + 2H2O → 2LiOH + H2
● Sodium + Water → Sodium Hydroxide + Hydrogen Gas
2Na + 2H2O
→ 2NaOH + H2
Reactions
with oxygen,O2
● to produce metal oxide.
● Lithium + oxygen → Lithium oxide
4Li + O2 → 2Li2O
● Sodium + oxygen → Sodium oxide
4Na + O2
→ 2Na2O
Reaction with Chlorine gas,Cl2
● to produce metal chloride.
● Lithium + Chlorine → Lithium chloride
2Li + Cl2
→ 2LiCl
● Sodium + Chlorine → Sodium chloride
2Na + Cl2
→ 2NaCl
Safety Precaution
● Alkali metals are very reactive.
● Therefore it must be kept in paraffin oil to prevent them from reacting with oxygen and water vapour in the air.『放进Paraffin Oil里面,防止G1金属和空气中的水分和氧气产生化学反应』
● We must avoid to hold group 1 metals with bare hand because they may react with water on our hand.『避免裸手拿取G1的金属,因为它可能和我们手的水分产生化学反应』
● We must wear safety goggles and gloves during handing experiment involving group 1 metal.『在做实验的时候,应该佩戴安全护目镜和手套』
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